Multifacetted study of a cretaceous coal with algal affinities—II. Composition of liquefaction products     

Z. Mudamburi  P.H. Given 《Organic Geochemistry》1985,8(3):221-231

Two hydrogen-rich lithobodies of highly alipathic character from a coal occurring in southwest Utah, have been studied. Bituminite (>50%), vitrinite (25–30%) and liptodetrinite (7–12%) are the principal macerals. The hexane-soluble products of hydrogenating the lithotypes at 400° with tetralin and hydrogen have been analyzed by GC-MS. Products identified include homologous series of alkylated naphthalenes, phenols, furans, cyclohexenones and hydroxy-pyridines. In the case of furans, the alkyl groups extend beyond C₃₀. Materials released by Soxhlet extraction with pyridine consist chiefly of homologous series of fatty acids and their methyl esters and of methyl alkyl ketones, which were not found in the hydrogenation products. The long alkyl chains in these substances can account for about 75% of the alkanes found in the hydrogenation products but not in the extracts. Most of the compounds mentioned in the foregoing are thought to be physically held or trapped in the coal, rather than chemically combined in its macromolecular network. Except for the fatty acids, the origins of these substances are difficult to identify.  相似文献   

Pyrolysis of immature Torbanite and of the resistant biopolymer (PRB A) isolated from extant alga Botryococcus braunii. Mechanism of formation and structure of torbanite     

C. Largeau  S. Derenne  E. Casadevall  A. Kadouri  N. Sellier 《Organic Geochemistry》1986,10(4-6)

Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C₃₁. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role.  相似文献   

宝顶山石窟造象岩壁风化产物化学特征及形成分析     

汪东云  谢本立 《工程地质学报》1995,3(3):18-30

为研究宝顶山石窟区造象岩壁风化破坏及渗水危害的作用机理,选择不同类型风化产物进行定期采样监测。本文重点论述了外围岩石和造象岩壁风化产物的化学成分及矿物成分、风化产物可溶盐的化学特征及可溶盐类型,以及这些特征的多年变化规律,分析论证了可溶盐不同水化学成因类型的形成特征,为防风化防渗水危害治理措施提供可靠依据。  相似文献   

卫星遥感系统中的政区信息拓扑          下载免费PDF全文

孙涵居为民  汤志成 《应用气象学报》1995,6(1):114-117

根据基层台站开展气象卫星监测作物长势等遥感业务的需要，给出了应用普通微机管理政区信息的拓扑方法。  相似文献   

Representativeness of total ozone trends as derived from satellite BUV and ground-based measurements     

Christos S. Zerefos  Christos C. Repapis  Roy L. Jenne 《Pure and Applied Geophysics》1982,120(1):29-53

The information content of the 7-year BUV data set has been reexamined by a comparison with a fairly large set of ground Dobson and M-83 instruments. The satellite-ground intercomparison of total ozone was done under different types of ground observation techniques (observation code) and different instrument exposure (exposure code) and for various distances of the subsatellite point from the station. Because of the existing latitudinal gradient in total ozone, at a given station the bias ground-BUV tends to be smaller when the subsatellite point is at a latitude higher than the station's latitude. Knowing the total ozone gradient at a given station, the BUV total ozone has been corrected to account for the ozone gradient and the correlation was calculated with the corresponding ground observations. These correlations seem to offer no improvement when compared with the correlations between the ground ozone and the actual BUV ozone at distances of the subsatellite point from the station within 200 km from the station used in previous studies. The seasonal variation of the BUV-ground correlation reveals information on the noise level of the measurements and the geographical distribution of the percentage mean bias: (Ground-BUV)×100/(Ground) is discussed. Both on short and on longer time scales it appears that the BUV derived recommended total ozone data set is reasonably good and possible instrumental drifts are not large. The analysis includes an extension through April 1977 of the BUV and contour-derived total ozone trends byLondon andLing (1980). Over the northern hemisphere both data sets (contour and BUV) show comparable trends over middle and high latitudes which range from –3 D.U./year to –5 D.U./year during the 7-year period April 1970–April 1977. In the southern hemisphere, however, long-term variation in total ozone cannot be determined from ground observations alone. It is concluded that for unknown reasons during the 7-year period of study, total ozone has been decreasing over most of the globe. The negative growth rates at high latitudes of the northern hemisphere are highly significant.  相似文献   

地球数字产品的空间数学基础   总被引：4，自引：0，他引：4  

胡鹏胡毓钜  吴艳兰杨传勇 李国建 《地球信息科学学报》2001,3(3):36-42

在分析当前地球数字产品空间数学基础局限性的基础上,将地图投影概念由传统的曲面到平面的变换扩展为曲面到曲面的变换,提出一套适合于大型GIS和地球数字产品的“地图投影”模型的实用模型,该模型的视图采用等距离切圆柱投影,度量空间是椭球面几何系统,符合计算机环境下GIS视图与度量空间分离的特性。鉴于全球多分辨率连续可视化,精密可视化量算,三维、多维地球数据统一,标准的空间定位框架和只有在统一的空间系统内全球资源、生态环境数据才能进行精确的地理分析等四个方面的需要,从地图投影进到本模型将是方向和技术趋势。  相似文献   

利用卫星云图作广西强降水短时预报   总被引：6，自引：2，他引：6  

林宗桂  陈冰廉 《广西气象》2005,26(4):1-4

构造天气学意义明确的卫星云图状态函数模型，在对云层进行分类的基础上，定量提取卫星云图参数，通过与云图模板的相似运算寻找短时预报指标。试报结果表明，这种方法对提高强降雨落区的短时预报准确率是可行的。  相似文献   

A MASCOTTE-based characterization of MCSs over Spain, 2000–2002     

R. García-Herrera  E. Hernndez  D. Paredes  D. Barriopedro  J.F. Correoso  L. Prieto 《Atmospheric Research》2005,73(3-4):261-282

A 3-year Mesoscale Convective Systems (MCSs) database, which extends from 2000 to 2002, has been built for the Iberian Peninsula and the Balearic Islands using the objective method MASCOTTE (MAximum Spatial COrrelation Technique). It was originally developed to track the evolution of convective systems over the Amazon region; after modifications, it is able to track MCS evolution even with an hour and a half of missed images and provides essential information of both dynamical and morphological characteristics of MCSs. MASCOTTE is tested against a visual and subjective method, and is found to offer advantages such as automation and a simple and efficient operation that make it very useful for building large MCS databases.Thirty-five MCSs were found between June and October, most of them originated along the Mediterranean coast and near the Pyrenees, showing an increasing occurrence from June to September, when the maximum is found. The regions most influenced by MCS occurrences are Balearic Islands, Valencia, Catalonia, Murcia and the Basque Country. The MCSs tend to be small, short-lived and linear, usually moving eastward or northeastward with low velocities.The MCSs-associated precipitation presents high variability, ranging from 80 to 0 mm h⁻¹ as maximum hourly records. Two different convective regions are identified based on MCS behavior in extreme precipitation events: Northern Spain (the Basque Country) with abundant and continuous precipitation regime but little MCS influence, and the Mediterranean coast, where precipitation is sporadic but much more intense.  相似文献   

一次MCS过程的卫星云图和数值模拟分析   总被引：1，自引：4，他引：1       下载免费PDF全文

顾亚进  唐洵昌等 《气象科学》2002,22(2):197-204

本文应用卫星云图与数值模拟结果对2000年6月2日发生的一次影响江苏的江淮气旋暴雨过程进行研究分析，阐述了这次暴雨过程表现的MCS基本特征。分析表明：MCS的形成可以由几个中β尺度对流云或对流带开始，在特定的环境场中汇合成合并；在其发展过程中必须维持湿度平流，低层到中层有暖平流，骨强偏南风急流伸向形成区，同时在其东北方向有一支高空西风急流相耦合；低层的辐合、整层凝结潜热的释放、垂直运动的增强、高层的辐散引起的正反馈机制是MCS发展的动因。  相似文献   

应用K指数和TOT指数作江苏中期降水预报的试验   总被引：3，自引：0，他引：3       下载免费PDF全文

宋海鸥  王永红等 《气象科学》2002,22(2):242-246

用国家气象中心的T63和T106中期数值预报产品，计算所划定区域的K指数和TOT指数作为预报因子，并统计与江苏省9个代表站降水的相关。用逐步回归方法建立了江苏省4－7月第4－6天的PP降水预报方程36个、MOS降水预报方程108个，多级判别临界值144组。在此基础上经统计制作江苏省降水概率预报。  相似文献